Thallium(III) selenite, Tl 2 (SeO 3 ) 3 | Zendy

Harrison William T. A. | Zendy

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Thallium(III) selenite, Tl 2 (SeO 3 ) 3

Author(s) -

Harrison William T. A.

Publication year - 2005

Publication title -

acta crystallographica section c

Language(s) - English

Resource type - Journals

eISSN - 1600-5759

pISSN - 0108-2701

DOI - 10.1107/s0108270105018111

Subject(s) - monoclinic crystal system , selenium , thallium , crystallography , lone pair , chemistry , group (periodic table) , materials science , physics , crystal structure , inorganic chemistry , molecule , organic chemistry

The structure of Tl 2 (SeO 3 ) 3 [dithallium(III) triselenium(IV) nonaoxide] is monoclinic ( P 2 1 / n symmetry), with all atoms in general positions. It is built up from TlO 6 octahedra, distorted TlO 7 pentagonal bipyramids and (SeO 3 ) 2− pyramids sharing vertices and edges to form corrugated (001) layers. The Se lone pairs of electrons are accommodated in the interlayer regions.

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