Open Access[(1 R ,2 R )‐2‐Amino‐1,2‐diphenyl‐ N ‐( p ‐tolylsulfonyl)ethylamido]chloro(η 6 ‐ethoxybenzene)ruthenium(II) methanol solvate
Author(s) -
Soleimannejad Janet,
Adams Harry,
White Colin
Publication year - 2005
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270104033815
Subject(s) - intramolecular force , chemistry , ruthenium , toluene , sulfonyl , hydrogen bond , medicinal chemistry , methanol , octahedron , stereochemistry , bond length , crystal structure , molecule , crystallography , catalysis , organic chemistry , alkyl
The title compound, [Ru(C 21 H 21 N 2 O 2 S)Cl(C 8 H 10 O)]·CH 4 O or [Ru(TsDPEN)Cl(η 6 ‐C 6 H 5 OCH 2 CH 3 )]·CH 4 O [where TsDPEN is (1 R ,2 R )‐1,2‐diphenyl‐ N ‐( p ‐toluenesulfonyl)ethylenediamine], contains an S ‐chiral Ru centre in a distorted octahedral environment, with similar bond lengths and angles to analogous complexes. The very short (N—)H⋯Cl distance of 2.61 Å is ascribed to an intramolecular hydrogen bond.