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3‐ tert ‐Butyl‐7,7‐di­methyl‐1‐phenyl‐5,6,7,8‐tetra­hydro­imidazo­[3,4‐ b ]­quinolin‐5‐one and 2,8,8‐tri­methyl‐5‐phenyl‐6,7,8,9‐tetrahydroimidazo­[2,3‐ a ]­quinolin‐6‐one: chains generated by C—H⋯N hydrogen bonds
Author(s) -
Low John N.,
Cobo Justo,
Mera Jaime,
Quiroga Jairo,
Glidewell Christopher
Publication year - 2004
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270104011291
Subject(s) - naphthalene , molecule , chemistry , ring (chemistry) , delocalized electron , stereochemistry , medicinal chemistry , hydrogen bond , organic chemistry
In both 3‐ tert ‐butyl‐7,7‐di­methyl‐1‐phenyl‐5,6,7,8‐tetra­hydro­imidazo­[3,4‐ b ]­quinolin‐5‐one, C 22 H 25 N 3 O, (I), and 2,8,8‐tri­methyl‐5‐phenyl‐6,7,8,9‐tetra­hydro­imidazo­[2,3‐ a ]­quinolin‐6‐one, C 19 H 19 N 3 O, (II), the heterobicyclic portions of the mol­ecules are planar, with naphthalene‐type delocalization in (II), while the carbocyclic ring in each compound adopts an envelope conformation. In both (I) and (II), the mol­ecules are linked weakly into chains by a single C—H⋯N hydrogen bond.

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