An Assessment of the Rubisco Inhibitor | Zendy

Erwin Beck | Zendy; Renate Scheibe | Zendy; Josef Reiner | Zendy

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An Assessment of the Rubisco Inhibitor

Author(s) -

Erwin Beck,

Renate Scheibe,

Josef Reiner

Publication year - 1989

Publication title -

plant physiology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.554

H-Index - 312

eISSN - 1532-2548

pISSN - 0032-0889

DOI - 10.1104/pp.90.1.13

Subject(s) - rubisco , phosphate , biochemistry , chemistry , chloroplast , pyruvate carboxylase , stereochemistry , photosynthesis , enzyme , gene

2-Carboxyarabinitol-1-phosphate, the nocturnal inhibitor of ribulose-1,5-bisphosphate carboxylase/oxygenase is identical with d-hamamelonic acid-2(1)-phosphate. Reasoning is based on theoretical considerations as well as on mass spectra and (1)H- and (13)C-NMR spectra of the phosphate-free compounds. d-Hamamelonic acid-2(1)-phosphate is interpreted as a metabolic derivative of d-hamamelose-2(1),5-bisphosphate which originates in the chloroplast from fructose-1,6-bisphosphate. A simple method for the synthesis of the inhibitor is suggested.

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