Some Synthetic Phytotoxins Structurally Related to Rhynchosporoside
Author(s) -
José Pío Beltrán,
Gary A. Strobel,
Ross C. Beier,
Bradford P. Mundy
Publication year - 1980
Publication title -
plant physiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.554
H-Index - 312
eISSN - 1532-2548
pISSN - 0032-0889
DOI - 10.1104/pp.65.3.554
Subject(s) - aglycone , glycosidic bond , glucoside , chemistry , stereochemistry , substrate (aquarium) , toxin , biochemistry , biology , glycoside , enzyme , medicine , ecology , alternative medicine , pathology
The (2-O)alpha-d-glucopyranoside of 1,2-propanediol and [U-(14)C]glucose were used as substrates in a reaction with almond beta-glucosidase, which resulted in the production of some (2-O)alpha-d-oligoglucosides of 1,2-propanediol. As its substrate, the beta-glucosidase preferred the glucoside isomer that rotates plane-polarized light to the right. Some of the glucosides produced in the enzymic reaction mixture possessed host selective toxin activity. It appears that the biological activity of the toxin is not dependent on the nature of the glycosidic linkage with the aglycone.
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