Anomalous Diffusion Profiles of Ag in CdTe due to Chemical Self-Diffusion
Author(s) -
H. Wolf,
F. Wagner,
Th. Wichert
Publication year - 2005
Publication title -
physical review letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.688
H-Index - 673
eISSN - 1079-7114
pISSN - 0031-9007
DOI - 10.1103/physrevlett.94.125901
Subject(s) - diffusion , self diffusion , materials science , stoichiometry , cadmium telluride photovoltaics , anomalous diffusion , analytical chemistry (journal) , chemical physics , thermodynamics , chemistry , nanotechnology , physics , innovation diffusion , knowledge management , self service , chromatography , marketing , computer science , business
Anomalous diffusion profiles of Ag in single crystalline CdTe were observed using the radiotracer 111Ag. The diffusion anneals were performed at 800 K under Cd or Te vapor and in a vacuum for different Ag concentrations. The measured Ag profiles directly reflect the distribution of the self-interstitials and vacancies of the Cd sublattice and are the result of chemical self-diffusion which describes the variation of the deviation from stoichiometry of the binary crystal as a function of depth and time.
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