Origin of Constant Loss in Ionic Conductors | Zendy

C. León | Zendy; A. Rivera | Zendy; A. Várez | Zendy; J. Sanz | Zendy; J. Santamarı́a | Zendy; K. L. Ngai | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Origin of Constant Loss in Ionic Conductors

Author(s) -

C. León,

A. Rivera,

A. Várez,

J. Sanz,

J. Santamarı́a,

K. L. Ngai

Publication year - 2001

Publication title -

physical review letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.688

H-Index - 673

eISSN - 1079-7114

pISSN - 0031-9007

DOI - 10.1103/physrevlett.86.1279

Subject(s) - omega , ionic bonding , condensed matter physics , electrical conductor , ionic conductivity , constant (computer programming) , conductivity , physics , crossover , ion , materials science , electrical resistivity and conductivity , low frequency , nuclear magnetic resonance , quantum mechanics , electrode , astronomy , artificial intelligence , computer science , electrolyte , programming language

We have analyzed the constant loss contribution to the ac conductivity in the frequency range 10 Hz-1 MHz and temperatures down to 8 K, for two Li ionic conductors, one crystalline (Li(0.18)La(0.61)TiO(3)) and the other glassy (61SiO(2);35Li(2)O.3Al(2)O3.P(2)O(5)). As temperature is increased a crossover is observed from a nearly constant loss to a fractional power law frequency dependence of the ac conductivity. At any fixed frequency omega, this crossover occurs at a temperature T such that omega approximately nu(0)exp(-E(m)/k(B)T), where nu(0) is the attempt frequency and E(m) is identified with the barrier for Li+ ions to leave their wells.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research