Hydrogen Molecules in Crystalline Silicon Treated with Atomic Hydrogen | Zendy

K. Murakami | Zendy; Naoki Fukata | Zendy; Shinichi Sasaki | Zendy; Kunie Ishioka | Zendy; Masahiro Kitajima | Zendy; Shigeto Fujimura | Zendy; Jun Kikuchi | Zendy; Hajime Haneda | Zendy

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Hydrogen Molecules in Crystalline Silicon Treated with Atomic Hydrogen

Author(s) -

K. Murakami,

Naoki Fukata,

Shinichi Sasaki,

Kunie Ishioka,

Masahiro Kitajima,

Shigeto Fujimura,

Jun Kikuchi,

Hajime Haneda

Publication year - 1996

Publication title -

physical review letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.688

H-Index - 673

eISSN - 1079-7114

pISSN - 0031-9007

DOI - 10.1103/physrevlett.77.3161

Subject(s) - silicon , hydrogen , deuterium , raman spectroscopy , atomic physics , molecule , materials science , kinetic isotope effect , hydrogen molecule , crystallography , physics , chemistry , optics , quantum mechanics , metallurgy

We report the first observation of the vibrational Raman spectrum of hydrogen molecules H2 in crystalline silicon treated with hydrogen atoms at 400 °C. The Raman spectrum of H2 in silicon observed at room temperature exhibits a frequency shift of around 4158 cm-1 and a very broad half-width of approximately 34 cm-1. An isotope shift was also detected at around 2990 cm-1 in silicon treated with deuterium atoms at 400 °C. The frequency shifts of the observed lines are in close agreement with those reported for H2 and D2 in the gas, liquid, and solid phases

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