Non-Arrhenius Conductivity in Glass: Mobility and Conductivity Saturation Effects | Zendy

Joseph Kincs | Zendy; Steve W. Martin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Non-Arrhenius Conductivity in Glass: Mobility and Conductivity Saturation Effects

Author(s) -

Joseph Kincs,

Steve W. Martin

Publication year - 1996

Publication title -

physical review letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.688

H-Index - 673

eISSN - 1079-7114

pISSN - 0031-9007

DOI - 10.1103/physrevlett.76.70

Subject(s) - arrhenius equation , conductivity , ionic conductivity , saturation (graph theory) , materials science , ion , omega , electrical resistivity and conductivity , activation energy , analytical chemistry (journal) , condensed matter physics , thermodynamics , physics , chemistry , electrode , quantum mechanics , mathematics , combinatorics , chromatography , electrolyte

Extreme non-Arrhenius dependence of the ionic conductivity in optimized fast ion conducting glasses has been observed. When all the chemical factors controlling the ionic conductivity in glass have been optimized, the conductivity fails to reach the values expected, .0.1 sV cmd21 at 298 K. A new series of glasses zAgI 1 s1 2 zd f0.525Ag2S 1 0.475B2S3:SiS2g have been measured for the first time and are found to exhibit a non-Arrhenius conductivity, the extent of which increases the greater the AgI content. Such behavior is believed to be a new feature of optimized fast ion conducting glasses and will be a critical obstacle to overcome if the conductivity of such systems is to ever reach the values needed for optimum device performance.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research