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Giant vibrations of impurity atoms on a crystal surface
Author(s) -
Robert E. Martinez,
Ernest Fontes,
J. A. Golovchenko,
J. R. Patel
Publication year - 1992
Publication title -
physical review letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.688
H-Index - 673
eISSN - 1079-7114
pISSN - 0031-9007
DOI - 10.1103/physrevlett.69.1061
Subject(s) - amplitude , debye model , condensed matter physics , crystal (programming language) , impurity , anisotropy , materials science , softening , surface (topology) , thermal , vibration , atomic physics , physics , molecular physics , thermodynamics , optics , quantum mechanics , geometry , mathematics , computer science , composite material , programming language
We have measured extremely large anisotropic thermal vibrations of gallium adatoms on a Si(111) surface using x-ray standing waves. At 830 K the rms amplitude normal to the surface is 0.47{plus minus}0.02 A while the parallel amplitude is 0.30{plus minus}0.02 A. The temperature dependence of these amplitudes deviates significantly from that expected from Debye theory and suggests a significant thermal softening of the surface bonding at elevated temperatures.

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