Electrostatic double-layer interaction between stacked charged bilayers | Zendy

Mafumi Hishida | Zendy; Yoko Nomura | Zendy; Ryo Akiyama | Zendy; Yasuhisa Yamamura | Zendy; Kazuya Saito | Zendy

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Electrostatic double-layer interaction between stacked charged bilayers

Author(s) -

Mafumi Hishida,

Yoko Nomura,

Ryo Akiyama,

Yasuhisa Yamamura,

Kazuya Saito

Publication year - 2017

Publication title -

physical review. e

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.896

H-Index - 304

eISSN - 2470-0053

pISSN - 2470-0045

DOI - 10.1103/physreve.96.040601

Subject(s) - dlvo theory , van der waals force , lamellar structure , ion , valence (chemistry) , electrostatics , double layer (biology) , chemical physics , materials science , electrostatic interaction , layer (electronics) , thermodynamics , chemistry , crystallography , physics , nanotechnology , molecule , colloid , organic chemistry

The inapplicability of the DLVO theory to multilayered anionic bilayers is found in terms of the co-ion-valence dependence of the lamellar repeat distance. Most of the added salt is expelled from the interlamellar space to the bulk due to the Gibbs-Donnan effect on multiple bilayers with the bulk. The electrostatic double-layer interaction is well expressed by the formula recently proposed by Trefalt. The osmotic pressure due to the expelled ions, rather than the van der Waals interaction, is the main origin of the attractive force between the bilayers

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