Capillary wave fluctuations and intrinsic widths of coupled fluid-fluid interfaces: An x-ray scattering study of a wetting film on bulk liquid
Author(s) -
Masafumi Fukuto,
Oleg Gang,
Kyle J. Alvine,
P. S. Pershan
Publication year - 2006
Publication title -
physical review e
Language(s) - English
Resource type - Journals
eISSN - 1550-2376
pISSN - 1539-3755
DOI - 10.1103/physreve.74.031607
Subject(s) - scattering , specular reflection , wetting , capillary wave , capillary action , physics , condensed matter physics , small angle scattering , optics , materials science , surface finish , thermodynamics , surface wave , composite material
An x-ray specular reflectivity (XR) and off-specular diffuse scattering (XDS) study of the coupled thermal capillary fluctuations and the intrinsic profiles of two interacting fluid-fluid interfaces is presented. The measurements are carried out on complete wetting films of perfluoromethylcyclohexane (PFMC) on the surface of bulk liquid eicosane (C20), as a function of film thickness 30infinity), determined by either the radius of gyration (5.3 A) or the bulk correlation length (4.8 A) of the alkane C20. The intrinsic liquid-vapor interfacial width is sharper (approximately 2 A) and remains essentially constant over the entire probed range of D .
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