Crystallization kinetics of polydisperse colloidal hard spheres. II. Binary mixtures

In this paper we present measurements of the crystallization kinetics of binary mixtures of two different sized hard sphere particles. The growth of the Bragg reflections over time were analyzed to yield the crystallite scattering vector, the total amount of crystal, and the average linear crystal size. It was observed that a particle size distribution skewed to higher sized particles has a less detrimental effect on the crystal structure than a skew to smaller sized particles. In the latter case we observe that initial crystallite growth occurs at only a small number of sites, with further crystallization sites developing at later times. Based on these measurements we elaborate further on the previously proposed growth mechanism whereby crystallization occurs in conjunction with a local fractionation process in the fluid, which significantly affects the kinetic growth of crystallites in polydisperse systems.