Hard-sphere and hard-disk freezing from the differential formulation of the generalized effective liquid approximation
Author(s) -
Carlos F. Tejero,
José A. Cuesta
Publication year - 1993
Publication title -
physical review. e, statistical physics, plasmas, fluids, and related interdisciplinary topics
Language(s) - English
Resource type - Journals
eISSN - 1095-3787
pISSN - 1063-651X
DOI - 10.1103/physreve.47.490
Subject(s) - hard spheres , compressibility , equation of state , spheres , phase (matter) , physics , thermodynamics , materials science , quantum mechanics , astronomy
We apply the differential formulation of the generalized effective liquid approximation to the study of hard-sphere and hard-disk freezing. We show that the thermodynamic properties of the solid phase are rather insensitive to the compressibility factor of the fluid phase used to map the solid onto the effective liquid. The solid-fluid coexistence data instead are quite dependent on the equation of state describing the fluid phase. Very accurate results, as compared with the simulation data, are obtained for both the freezing of hard spheres and hard disks
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom