Anomalous excitons and screenings unveiling strong electronic correlations inSrTi 1 − x Nb x O 3
Author(s) -
Pranjal Kumar Gogoi,
Lorenzo Sponza,
Daniel Schmidt,
Teguh Citra Asmara,
Caozheng Diao,
Jason Lim,
Sock Mui Poh,
Shinichi Kimura,
Paolo E. Trevisanutto,
Valério Olevano,
Andrivo Rusydi
Publication year - 2015
Publication title -
physical review b
Language(s) - English
Resource type - Journals
eISSN - 1538-4489
pISSN - 1098-0121
DOI - 10.1103/physrevb.92.035119
Subject(s) - exciton , delocalized electron , physics , electron , condensed matter physics , atomic physics , quantum mechanics
International audienceElectron-electron (e-e) and electron-hole (e-h) interactions are often associated with many exotic phenomena in correlated electron systems. Here, we report an observation of anomalous excitons at 3.75 , 4.67 and 6.11 eV at 4.2 K in bulk-SrTiO$_3$. Fully supported by ab initio GW Bethe-Salpeter equation calculations, these excitons are due to surprisingly strong e-h and e-e interactions with different characters: 4.67 and 6.11 eV are resonant excitons and 3.75 eV is a bound Wannier-like exciton with an unexpectedly higher level of delocalization. Measurements and calculations on SrTi$_{1-x}$Nb$_x$O$_3$ for 0.0001$\leq$x$\leq$0.005 further show that energy and spectral-weight of the excitonic peaks vary as a function of electron doping (x) and temperature, which are attributed to screening effects. Our results show the importance of e-h and e-e interactions yielding to anomalous excitons and thus bring out a new fundamental perspective in SrTiO$_3$
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