Insulator-to-metal transition and correlated metallic state of V2 O3 investigated by optical spectroscopy
Author(s) -
M. K. Stewart,
D. Brownstead,
S. Wang,
K. West,
Juan Gabriel Ramírez,
M. M. Qazilbash,
Natalia B. Perkins,
Iván K. Schuller,
D. N. Basov
Publication year - 2012
Publication title -
physical review b
Language(s) - English
Resource type - Journals
eISSN - 1538-4489
pISSN - 1098-0121
DOI - 10.1103/physrevb.85.205113
Subject(s) - quasiparticle , metal , metal–insulator transition , materials science , spectral line , physics , condensed matter physics , optical conductivity , mott transition , hubbard model , superconductivity , quantum mechanics , metallurgy
The optical properties of V${}_{2}$O${}_{3}$ thin films are investigated across the insulator-to-metal transition and in the metallic state. The spectral weight transfer observed across the transition, over an energy scale of 5 eV, is consistent with the Mott-Hubbard model for correlated electron systems. In the metallic phase, a strong Drude peak is observed, which exhibits a pronounced temperature dependence related to the transfer of states from the Hubbard bands to the quasiparticle peaks as the temperature is reduced. The analysis of the far-infrared spectra reveals signatures of strong electronic correlations in V${}_{2}$O${}_{3}$. Finally, a comparison to VO${}_{2}$ data is presented.
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