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Magnetic and crystal structures of the magnetoelectric pyroxeneLiCrSi2O6
Author(s) -
Gwilherm Nénert,
Masahiko Isobe,
C. Ritter,
O. Isnard,
A. N. Vasiliev,
Yutaka Ueda
Publication year - 2009
Publication title -
physical review b
Language(s) - English
Resource type - Journals
eISSN - 1538-4489
pISSN - 1098-0121
DOI - 10.1103/physrevb.79.064416
Subject(s) - antiferromagnetism , condensed matter physics , octahedron , frustration , physics , order (exchange) , ferromagnetism , coupling (piping) , neutron diffraction , crystal structure , crystallography , materials science , diffraction , quantum mechanics , chemistry , economics , metallurgy , finance
International audienceWe investigated the magnetic and crystal structures of the recent reported magnetoelectric system LiCrSi2O6 by powder neutron diffraction. Below TN=11.5 K, an antiferromagnetic order appears. It is characterized by an antiferromagnetic coupling within the CrO6 octahedra chains and a ferromagnetic coupling between the chains. The magnetic order is commensurate with the lattice with k=0. The associated magnetic space group is P21 /c. This symmetry is in agreement with the reported magnetoelectric effect. We show that the magnetic frustration in this system is small. Finally, we discuss our results using a Landau phenomenological model and in the light of the literature

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