Microstructural analysis of twinnedβ − Gd 5 Si 2 Ge
Author(s) -
John Meyers,
Scott Chumbley,
Wonyoung Choe,
Gordon J. Miller
Publication year - 2002
Publication title -
physical review. b, condensed matter
Language(s) - English
Resource type - Journals
eISSN - 1095-3795
pISSN - 0163-1829
DOI - 10.1103/physrevb.66.012106
Subject(s) - crystal twinning , crystallography , materials science , transmission electron microscopy , diffraction , microstructure , physics , nanotechnology , chemistry , optics
The room-temperature microstructure of the giant magnetocaloric material Gd 5 Si 2 Ge 2 is investigated using transmission electron microscopy and selected area diffraction. Nonmerohedral twinning is identified and its twinlaw, which relates one twin component to the other, is revealed. Based on selected area diffraction pattern data, we build a structural model for nonmerohedral twinning and explain its origin in terms of the irregular shear movement of two-dimensional ∞ 2 [Gd 5 (Si 2 Ge 2 )] slabs held together by (Si,Ge) dimers.
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