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Hysteresis shift in Fe-filled carbon nanotubes due to γ-Fe
Author(s) -
C. Prados,
P. Crespo,
J. M. González,
A. Hernando,
José F. Marco,
R. Gancedo,
Nicole Grobert,
Mauricio Terrones,
R. M. Walton,
Harold W. Kroto
Publication year - 2002
Publication title -
physical review. b, condensed matter
Language(s) - English
Resource type - Journals
eISSN - 1095-3795
pISSN - 0163-1829
DOI - 10.1103/physrevb.65.113405
Subject(s) - materials science , hysteresis , carbon nanotube , phase (matter) , mössbauer spectroscopy , antiferromagnetism , ferrocene , condensed matter physics , carbon fibers , magnetic hysteresis , spectroscopy , characterization (materials science) , analytical chemistry (journal) , nuclear magnetic resonance , chemical physics , magnetic field , nanotechnology , crystallography , magnetization , composite material , chemistry , physics , composite number , electrochemistry , electrode , quantum mechanics , chromatography
The phase distribution of high aspect ratio, Fe-filled carbon nanotubes prepared by pyrolyzing a mixture of powered ferrocene and C_(60) has been determined by means of Mössbauer spectroscopy. Our results for that characterization are closely related to the observation, after field cooling processes, of a hysteresis loop shift and clearly suggest a spatial phase distribution which includes the presence of a g-Fe/α-Fe interface. The temperature ependence of the hysteresis loop shift is discussed in terms of localized regions at that interface exhibiting uncompensated antiferromagnetism within reduced dimensions

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