Multiwalled carbon nanotubes grown in hydrogen atmosphere: An x-ray diffraction study
Author(s) -
Yutaka Maniwa,
Ryuji Fujiwara,
Hiroshi Kira,
Hideki Tou,
Eiji Nishibori,
Masaki Takata,
Makoto Sakata,
Akihiko Fujiwara,
Xinluo Zhao,
Sumio Iijima,
Yukio Ando
Publication year - 2001
Publication title -
physical review. b, condensed matter
Language(s) - English
Resource type - Journals
eISSN - 1095-3795
pISSN - 0163-1829
DOI - 10.1103/physrevb.64.073105
Subject(s) - atmosphere (unit) , diffraction , graphite , hydrogen , materials science , carbon nanotube , physics , nanotube , crystallography , atomic physics , nanotechnology , optics , composite material , thermodynamics , chemistry , quantum mechanics
X-ray diffraction study of multiwalled carbon nanotube (MWNT) grown by arc discharge in hydrogen atmosphere is presented. It is found that the thermal-expansion coefficient along the radial direction of MWNT is widely distributed in a range from 1.6 x 10{sup -5} K{sup -1} to 2.6 x 10{sup -5} K{sup -1}, indicating the existence of both of Russian doll MWNT and highly defective MWNT. Russian doll MWNT is suggested to have the outer diameter less than {approx}100 Aa. Thicker MWNT's are typically highly defective, and may have the jelly roll (scroll) or defective polygonal structure consisting of flat graphite domains.
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