Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study | Zendy

P. Giridhar Reddy | Zendy; K. Ramesh | Zendy; S. Shylaja | Zendy; K. C. Rajanna | Zendy; Sushama Kandlikar | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study

Author(s) -

P. Giridhar Reddy,

K. Ramesh,

S. Shylaja,

K. C. Rajanna,

Sushama Kandlikar

Publication year - 2012

Publication title -

the scientific world journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.453

H-Index - 93

eISSN - 2356-6140

pISSN - 1537-744X

DOI - 10.1100/2012/456516

Subject(s) - ketone , n bromosuccinimide , acetone , chemistry , catalysis , acetic acid , aqueous solution , kinetics , organic chemistry , medicinal chemistry , halogenation , physics , quantum mechanics

Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research