Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair | Zendy

Jennifer Möricke | Zendy; Birgit Wibbeling | Zendy; Constantin G. Daniliuc | Zendy; Gerald Kehr | Zendy; Gerhard Erker | Zendy

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Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair

Author(s) -

Jennifer Möricke,

Birgit Wibbeling,

Constantin G. Daniliuc,

Gerald Kehr,

Gerhard Erker

Publication year - 2017

Publication title -

philosophical transactions of the royal society a mathematical physical and engineering sciences

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.074

H-Index - 169

eISSN - 1471-2962

pISSN - 1364-503X

DOI - 10.1098/rsta.2017.0015

Subject(s) - frustrated lewis pair , lewis acids and bases , borane , enamine , electron pair , chemistry , boron , polymer chemistry , organic chemistry , catalysis , electron , physics , quantum mechanics

The conjugated dienamine4 selectively adds Piers' borane [HB(C6 F5 )2 ] to give the enamine/borane system5 , which features a boratirane structure by internal enamine carbon Lewis base to boron Lewis acid interaction. Compound5 behaves as a C/B frustrated Lewis pair and undergoes typical addition reactions to benzaldehyde, several nitriles and to sulfur dioxide.This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

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