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Catalysts for CO 2 /epoxide ring-opening copolymerization
Author(s) -
Gemma Trott,
Poonam Saini,
Charlotte K. Williams
Publication year - 2016
Publication title -
philosophical transactions of the royal society a mathematical physical and engineering sciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.074
H-Index - 169
eISSN - 1471-2962
pISSN - 1364-503X
DOI - 10.1098/rsta.2015.0085
Subject(s) - copolymer , epoxide , catalysis , polymer , commodity , materials science , ring (chemistry) , carbon dioxide , polymer science , organic chemistry , chemistry , business , composite material , finance
This article summarizes and reviews recent progress in the development of catalysts for the ring-opening copolymerization of carbon dioxide and epoxides. The copolymerization is an interesting method to add value to carbon dioxide, including from waste sources, and to reduce pollution associated with commodity polymer manufacture. The selection of the catalyst is of critical importance to control the composition, properties and applications of the resultant polymers. This review highlights and exemplifies some key recent findings and hypotheses, in particular using examples drawn from our own research.

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