XIV. On the spontaneous crystallisation of monochloracetic acid and its mixtures with naphthalene | Zendy

H. A. Miers | Zendy; Florence Isaac | Zendy

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XIV. On the spontaneous crystallisation of monochloracetic acid and its mixtures with naphthalene

Author(s) -

H. A. Miers,

Florence Isaac

Publication year - 1909

Publication title -

philosophical transactions of the royal society of london series a containing papers of a mathematical or physical character

Language(s) - English

Resource type - Journals

eISSN - 2053-9258

pISSN - 0264-3952

DOI - 10.1098/rsta.1909.0014

Subject(s) - crystallization , naphthalene , eutectic system , chemistry , crystallography , thermodynamics , materials science , chemical engineering , organic chemistry , physics , engineering , microstructure

Our previous papers on spontaneous crystallisation have dealt with the supersolubility curves, firstly, of pure substances; secondly, of mixtures of two or more substances which do not form mixed crystals; and, finally, with naphthalene andβ -naphthol; the last form mixed crystals of the type (l) of Roozeboom, in which the freezingpoints of all mixtures lie between the freezing-points of the pure components. The object for which the present investigation was undertaken was to study the spontaneous crystallisation of two substances which form mixed crystals and possess a minimum or eutectic freezing-point.

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