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On some electro-nitrogurets
Author(s) -
W.R. Grove
Publication year - 1843
Publication title -
abstracts of the papers printed in the philosophical transactions of the royal society of london
Language(s) - English
Resource type - Journals
eISSN - 2053-9142
pISSN - 0365-5695
DOI - 10.1098/rspl.1837.0145
Subject(s) - cathode , ammonia , anode , solid state , metallurgy , alloy , metal , hydrogen , fusible alloy , materials science , chemistry , inorganic chemistry , electrode , organic chemistry
The author states that he has made many attempts to render permanent the ammoniacal amalgam, and that he has succeeded in freezing it by means of solid carbonic acid, during which solidification, and also while in its solid state, it underwent no chemical change. He subsequently attempted to procure a permanent compound by electrolyzing a solution of hydrochlorate of ammonia with an extremely fusible alloy at the cathode; but this attempt was unsuccessful. It then occurred to him, that by using an oxidable metal at the anode, which could be revived in conjunction with nascent hydrogen and nitrogen at the cathode, one or both of these elements might be combined with the solid metal, and so form permanent compounds.

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