Influence of dopant substitution mechanism on catalytic properties within hierarchical architectures | Zendy

Stephanie H. Newland | Zendy; Wharton Sinkler | Zendy; Thomas M. Mezza | Zendy; Simon R. Bare | Zendy; Robert Raja | Zendy

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Influence of dopant substitution mechanism on catalytic properties within hierarchical architectures

Author(s) -

Stephanie H. Newland,

Wharton Sinkler,

Thomas M. Mezza,

Simon R. Bare,

Robert Raja

Publication year - 2016

Publication title -

proceedings of the royal society a mathematical physical and engineering sciences

Language(s) - English

Resource type - Journals

eISSN - 1471-2946

pISSN - 1364-5021

DOI - 10.1098/rspa.2016.0095

Subject(s) - dopant , catalysis , beckmann rearrangement , characterization (materials science) , materials science , transition metal , phase (matter) , porosity , chemical engineering , combinatorial chemistry , chemistry , nanotechnology , doping , organic chemistry , optoelectronics , engineering

A range of hierarchically porous (HP) AlPO-5 catalysts, with isomorphously substituted transition metal ions, have been synthesized using an organosilane as a soft template. By employing a range of structural and spectroscopic characterization protocols, the properties of the dopant-substituted species within the HP architectures have been carefully evaluated. The resulting nature of the active site is shown to have a direct impact on the ensuing catalytic properties in the liquid-phase Beckmann rearrangement of cyclic ketones.

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