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One-dimensional hydrogen atom
Author(s) -
R. Loudon
Publication year - 2016
Publication title -
proceedings of the royal society a mathematical physical and engineering sciences
Language(s) - English
Resource type - Journals
eISSN - 1471-2946
pISSN - 1364-5021
DOI - 10.1098/rspa.2015.0534
Subject(s) - singularity , limiting , hydrogen atom , schrödinger equation , atom (system on chip) , range (aeronautics) , dimension (graph theory) , zero (linguistics) , physics , quantum mechanics , mathematical physics , mathematics , mathematical analysis , materials science , pure mathematics , computer science , group (periodic table) , mechanical engineering , linguistics , philosophy , engineering , composite material , embedded system
The theory of the one-dimensional (1D) hydrogen atom was initiated by a 1952 paper but, after more than 60 years, it remains a topic of debate and controversy. The aim here is a critique of the current status of the theory and its relation to relevant experiments. A 1959 solution of the Schrödinger equation by the use of a cut-off atx =a to remove the singularity at the origin in the 1/|x | form of the potential is clarified and a mistaken approximation is identified. The singular atom is not found in the real world but the theory with cut-off has been applied successfully to a range of four practical three-dimensional systems confined towards one dimension, particularly their observed large increases in ground state binding energy. The true 1D atom is in principle restored when the short distancea tends to zero but it is sometimes claimed that the solutions obtained by the limiting procedure differ from those obtained by solution of the basic Schrödinger equation without any cut-off in the potential. The treatment of the singularity by a limiting procedure for applications to practical systems is endorsed.

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