Supra-molecular assembly of aromatic proton sponges to direct the crystallization of extra-large-pore zeotypes | Zendy

Raquel MartínezFranco | Zendy; Junliang Sun | Zendy; Germán Sastre | Zendy; Yifeng Yun | Zendy; Xiaodong Zou | Zendy; Manuel Moliner | Zendy; Avelino Corma | Zendy

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Supra-molecular assembly of aromatic proton sponges to direct the crystallization of extra-large-pore zeotypes

Author(s) -

Raquel MartínezFranco,

Junliang Sun,

Germán Sastre,

Yifeng Yun,

Xiaodong Zou,

Manuel Moliner,

Avelino Corma

Publication year - 2014

Publication title -

proceedings of the royal society a mathematical physical and engineering sciences

Language(s) - English

Resource type - Journals

eISSN - 1471-2946

pISSN - 1364-5021

DOI - 10.1098/rspa.2014.0107

Subject(s) - naphthalene , magic angle spinning , molecule , crystallization , zeolite , spectroscopy , fluorescence spectroscopy , proton , nuclear magnetic resonance spectroscopy , chemistry , crystallography , magic angle , materials science , fluorescence , stereochemistry , organic chemistry , catalysis , physics , optics , quantum mechanics

The combination of different experimental techniques, such as solid (13)C and (1)H magic-angle spinning NMR spectroscopy, fluorescence spectroscopy and powder X-ray diffraction, together with theoretical calculations allows the determination of the unique structure directing the role of the bulky aromatic proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) towards the extra-large-pore ITQ-51 zeolite through supra-molecular assemblies of those organic molecules.

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