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Single-atom active sites on metal-organic frameworks
Author(s) -
Marco Ranocchiari,
C. Lothschütz,
Daniel Grolimund,
Jeroen A. van Bokhoven
Publication year - 2012
Publication title -
proceedings of the royal society a mathematical physical and engineering sciences
Language(s) - English
Resource type - Journals
eISSN - 1471-2946
pISSN - 1364-5021
DOI - 10.1098/rspa.2012.0078
Subject(s) - catalysis , homogeneous , heterogeneous catalysis , moiety , metal organic framework , mesoporous material , homogeneous catalysis , mesoporous silica , porosity , nanotechnology , materials science , metal , atom (system on chip) , active site , chemistry , combinatorial chemistry , organic chemistry , computer science , adsorption , physics , thermodynamics , embedded system
Single-site heterogeneous catalysis has been recently accepted as a novel branch of heterogeneous catalysis. Catalysts with single-atom active sites (SAHCs) allow the design and fine-tuning of the active moiety, and can potentially combine the advantages of heterogeneous and homogeneous catalysis. This study illustrates how porous metal-organic frameworks (MOFs) can be synthesized with homogeneous distribution of SAHCs. The catalytic potential of MIXMOFs is shown. A short overview of catalysis with mesoporous silica materials is described to demonstrate their importance in SAHC.

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