Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts | Zendy

Nataliya V. Maksimchuk | Zendy; Olga V. Zalomaeva | Zendy; Igor Y. Skobelev | Zendy; Konstantin A. Kovalenko | Zendy; Vladimir P. Fedin | Zendy; Oxana A. Kholdeeva | Zendy

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Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts

Author(s) -

Nataliya V. Maksimchuk,

Olga V. Zalomaeva,

Igor Y. Skobelev,

Konstantin A. Kovalenko,

Vladimir P. Fedin,

Oxana A. Kholdeeva

Publication year - 2012

Publication title -

proceedings of the royal society a mathematical physical and engineering sciences

Language(s) - English

Resource type - Journals

eISSN - 1471-2946

pISSN - 1364-5021

DOI - 10.1098/rspa.2012.0072

Subject(s) - catalysis , mesoporous material , leaching (pedology) , metal , metal organic framework , heterogeneous catalysis , materials science , chemistry , inorganic chemistry , chemical engineering , organic chemistry , environmental science , adsorption , soil science , engineering , soil water

In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O2 and tert-butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO2. A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst's resistance to metal leaching and the nature of catalysis.

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