
Thermo-dynamics of stationary systems II—The diffusion element
Publication year - 1935
Publication title -
proceedings of the royal society of london. series a, mathematical and physical sciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.814
H-Index - 135
eISSN - 2053-9169
pISSN - 0080-4630
DOI - 10.1098/rspa.1935.0172
Subject(s) - element (criminal law) , diffusion , notice , statistical physics , dynamics (music) , mathematical economics , computer science , mathematics , physics , thermodynamics , law , political science , acoustics
Continuing the analysis of stationary states, we find that the thermodynamics of the diffusion element seem to be even more wanting in clarity than the thermo-dynamics of the thermo-element. In the theory of the diffusion element we notice first of all the absence of a general thermo-dynamic treatment comparable to the treatment which Boltzmann worked out for thermo-element. Instead of that we find the statements of the osmotic theory which, so far as the diffusion element is concerned, are expressed neither in a purely thermo-dynamic nor in a purely dynamic form, and remain, on this account, in a rather uncertain relation to thermo-dynamic principles. This causes an absence of any resemblance whatsoever between the formal results of the current theories dealing with the two stationary states.