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The dark interval in mercury fluorescence
Author(s) -
Lord Rayleigh
Publication year - 1934
Publication title -
proceedings of the royal society of london series a containing papers of a mathematical and physical character
Language(s) - English
Resource type - Journals
eISSN - 2053-9150
pISSN - 0950-1207
DOI - 10.1098/rspa.1934.0153
Subject(s) - mercury (programming language) , fluorescence , excitation , excited state , atomic physics , resonance fluorescence , aluminium , chemistry , materials science , physics , optics , metallurgy , quantum mechanics , computer science , programming language
This phenomenon was originally described by R. W. Wood. He found that when a rapidly moving current of mercury vapour was excited by the aluminium spark, the green fluorescence did not start at the point at which excitation was applied, but that as interval could be observed in which the vapour was dark. He also found that the fluorescence of wave-length 2537 corresponding to the resonance line, which accompanies the green fluorescence, showed a dark interval. Some other authors have also written on this effect. Pienkowski obtained it under certain conditions with mercury arc excitation, but left it open whether the excitation was to be considered atomic or molecular. It has also been discussed by Gaviola. It seemed that further work was called for since the dark interval phenomenon may be crucial for determining the real relationship between the numerous and complicated phenomenon of mercury fluorescence.

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