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The influence of nitrogen peroxide on the combination of hydrogen and oxygen
Author(s) -
Harold Warris Thompson,
Cyril Norman Hinshelwood
Publication year - 1929
Publication title -
proceedings of the royal society of london series a containing papers of a mathematical and physical character
Language(s) - English
Resource type - Journals
eISSN - 2053-9150
pISSN - 0950-1207
DOI - 10.1098/rspa.1929.0109
Subject(s) - hydrogen peroxide , oxygen , nitrogen , chemistry , hydrogen , limiting , inorganic chemistry , peroxide , biochemistry , organic chemistry , mechanical engineering , engineering
It has recently been shown that small traces of nitrogen peroxide exert a remarkable influence on the combination of hydrogen and oxygen, even at temperatures far below that at which the normal reaction has an appreciable velocity. At any such temperature there exist two sharply defined critical concentrations of nitrogen peroxide, between which there is instantaneous inflammation of the hydrogen and oxygen, but above or below which there is only an extremely slow reaction. The transition at each of these nitrogen peroxide pressures is very abrupt. An analogues phenomenon can be observed in the union of oxygen and hydrogen alone. Between certain limiting concentrations there is immediate explosion, but above and below these a reaction with a measurable velocity takes place.

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