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The fundamental equations of quantum mechanics
Author(s) -
P. A. M. Dirac
Publication year - 1925
Publication title -
proceedings of the royal society of london series a containing papers of a mathematical and physical character
Language(s) - English
Resource type - Journals
eISSN - 2053-9150
pISSN - 0950-1207
DOI - 10.1098/rspa.1925.0150
Subject(s) - bohr model , correspondence principle (sociology) , classical physics , physics , theoretical physics , classical electromagnetism , classical mechanics , quantum mechanics , action (physics) , stationary state , quantum , mathematics , economics , market economy
It is well known that the experimental facts of atomic physics necessitate a departure from the classical theory of electrodynamics in the description of atomic phenomena. This departure takes the form, in Bohr’s theory, of the special assumptions of the existence of stationary states of an atom, in which it does not radiate, and of certain rules, called quantum conditions, which fix the stationary states and the frequencies of the radiation emitted during transitions between them. These assumptions are quite foreign to the classical theory, but have been very successful in the interpretation of a restricted region of atomic phenomena. The only way in which the classical theory is used is through the assumption that the classical laws hold for the description of the motion in the stationary states, although they fail completely during transitions, and the assumption, called the Correspondence Principle, that the classical theory gives the right results in the limiting case when the action per cycle of the system is large compared to Planck’s constanth , and in certain other special cases. In a recent paper Heisenberg puts forward a new theory, which suggests that it is not the equations of classical mechanics that are in any way at fault, but that the mathematical operations by which physical results are deduced from them require modification.All the information supplied by the classical theory can thus be made use of in the new theory.

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