Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview | Zendy

Kayla A. DeNike | Zendy; Stefan M. Kilyanek | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview

Author(s) -

Kayla A. DeNike,

Stefan M. Kilyanek

Publication year - 2019

Publication title -

royal society open science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.84

H-Index - 51

ISSN - 2054-5703

DOI - 10.1098/rsos.191165

Subject(s) - catalysis , yield (engineering) , homogeneous , vicinal , product distribution , homogeneous catalysis , commodity chemicals , chemistry , reaction mechanism , catalytic cycle , biochemical engineering , materials science , organic chemistry , combinatorial chemistry , thermodynamics , physics , metallurgy , engineering

Deoxydehydration (DODH) is an important reaction for the upconversion of biomass-derived polyols to commodity chemicals such as alkenes and dienes. DODH can be performed by a variety of early metal-oxo catalysts incorporating Re, Mo and V. The varying reduction methods used in the DODH catalytic cycle impact the product distribution, reaction mechanism and the overall yield of the reaction. This review surveys the reduction methods commonly used in homogeneous DODH catalyst systems and their impacts on yield and reaction conditions.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research