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Nanostructured tungsten oxide (WO 3 ) particles were prepared in aqueous solution by mimicking biomineralization. Precursor WO 3  · H 2 O particles were generated by ageing a 60°C (NH 4 ) 10 W 12 O 41  · 5H 2 O solution containing gelatin. This was followed by heating to 600°C in air for thermal conversion to WO 3 . The addition of gelatin led to the formation of layered structures consisting of WO 3  · H 2 O platy particles, which contained segmented, block-like nanoscale units. The macroscopic layered structure was preserved after thermal conversion to WO 3 , while the morphology of the block-like units changed to orthogonally crossed nanorods.

Biomimetic synthesis of nanostructured WO 3 · H 2 O particles and subsequent thermal conversion to WO 3

Biomimetic synthesis of nanostructured WO ₃ · H ₂ O particles and subsequent thermal conversion to WO ₃