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It has been reported that the introduction of reduced graphene oxide (RGO) can enhance the crystallization and orientation of high-density polyethylene (HDPE) matrix and thus improve the mechanical properties of HDPE/RGO nanocomposites. In this study, the local microstructures and orientations in different regions of HDPE/RGO bars with varied RGO contents were further explored by two-dimensional small-angle X-ray scattering using a microbeam technique. It is unveiled that the orientation orderings of each position is intensified with increasing RGO amount, and of particular interest is the observation of the slight change of the ordering degrees in diverse zones of HDPE/RGO nanocomposite bars, indicating that RGO imposes a uniform enhancing effect upon HDPE matrix within different areas and consequently induces an effective increase of the mechanical properties of HDPE/RGO nanocomposites.

royal society open science

Microbeam two-dimensional small-angle X-ray scattering investigating the effects of reduced graphene oxide on local microstructures of high-density polyethylene/reduced graphene oxide nanocomposite bars