Rapid and sensitive detection of uranyl ion with citrate-stabilized silver nanoparticles by the surface-enhanced Raman scattering technique
Author(s) -
Jiaolai Jiang,
Shaofei Wang,
Hui Deng,
Haoxi Wu,
Jun Chen,
Junsheng Liao
Publication year - 2018
Publication title -
royal society open science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.84
H-Index - 51
ISSN - 2054-5703
DOI - 10.1098/rsos.181099
Subject(s) - uranyl , uranium , detection limit , raman scattering , silver nanoparticle , ion , nanoparticle , raman spectroscopy , contamination , materials science , chemistry , nanotechnology , analytical chemistry (journal) , chromatography , optics , metallurgy , physics , ecology , organic chemistry , biology
Uranium contamination poses a huge threat to human health due to its widespread use in the nuclear industry and weapons. We proposed a simple and convenient wet-state SERS method for uranyl detection based on the citrate-stabilized silver nanoparticles. The effect of citrate on the detection performance was also discussed. By using the citrate as an internal reference to normalize the peak of uranyl, a quantitative analysis was achieved and a good linear relationship of uranyl concentration from 0.2 to 5 µM with the limit of detection of 60 nM was obtained. With its simplicity, convenience and cost-effectiveness, this method has great potential for the detection of other molecules also.
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