Donor–acceptor Stenhouse adduct-grafted polycarbonate surfaces: selectivity of the reaction for secondary amine on surface | Zendy

Sukhdeep Singh | Zendy; Patrick Mai | Zendy; Justyna Borowiec | Zendy; Yixin Zhang | Zendy; Yong Lei | Zendy; Andreas Schober | Zendy

Open Access

Donor–acceptor Stenhouse adduct-grafted polycarbonate surfaces: selectivity of the reaction for secondary amine on surface

Author(s) -

Sukhdeep Singh,

Patrick Mai,

Justyna Borowiec,

Yixin Zhang,

Yong Lei,

Andreas Schober

Publication year - 2018

Publication title -

royal society open science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.84

H-Index - 51

ISSN - 2054-5703

DOI - 10.1098/rsos.180207

Subject(s) - amine gas treating , polycarbonate , reactivity (psychology) , selectivity , grafting , adduct , chemoselectivity , acceptor , tertiary amine , polymer chemistry , surface modification , chemistry , polymer , materials science , organic chemistry , photochemistry , catalysis , medicine , alternative medicine , physics , pathology , condensed matter physics

Donor–acceptor Stenhouse adducts (DASAs) are gaining attention from organic and material chemists due to their visible light-stimulated photochromic properties. In this report, we present a facile method for grafting coloured triene on polycarbonate surface, without involving any pre-treatments like plasma activation, etc. The chemoselectivity of carbonate with a primary amine and Meldrum's activated furan (MAF) with polymer bound secondary amine has been exploited to graft photoswitchable DASA on the polymer surface. Primary, secondary and tertiary amine-functionalized polycarbonate surfaces have been prepared to evaluate the reactivity of amine with MAF.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research