Open AccessSensing study of quinoxaline analogues with theoretical calculation, single-crystal X-ray structure and real application in commercial fruit juices
Author(s) -
Surajit Chakraborty,
Shyamaprosad Goswami,
Ching Kheng Quah,
Bholanath Pakhira
Publication year - 2018
Publication title -
royal society open science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.84
H-Index - 51
ISSN - 2054-5703
DOI - 10.1098/rsos.180149
Subject(s) - quinoxaline , chemistry , crystallography , crystal structure , organic chemistry
Single-crystal X-ray structures of dimeric quinoxaline aldehyde (QA), quinoxaline dihydrazone (DHQ) and HQNM (Goswami S et al. 2013 Tetrahedron Lett. 54 , 5075–5077. ( doi:10.1016/j.tetlet.2013.07.051 ); Goswami S et al. 2014 RSC Adv. 4 , 20 922–20 926. ( doi:10.1039/C4RA00594E ); Goswami S et al. 2014 New J. Chem. 38 , 6230–6235. ( doi:10.1039/C4NJ01498G )) are reported along with the theoretical study. Among them, QA is not acting as an active probe, but DHQ and HQNM are serving as selective and sensitive probe for the Fe 3+ cation and the Ni 2+ cation, respectively. DHQ can also detect the Fe 3+ in commercial fruit juices (grape and pomegranate).