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Alan McLeod Sargeson FAA. 13 October 1930 — 29 December 2008
Author(s) -
B. Bosnich
Publication year - 2011
Publication title -
biographical memoirs of fellows of the royal society
Language(s) - English
Resource type - Journals
eISSN - 1748-8494
pISSN - 0080-4606
DOI - 10.1098/rsbm.2011.0017
Subject(s) - cobalt , chemistry , reactivity (psychology) , hydrolysis , transition metal , coordination complex , metal , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , medicine , catalysis , alternative medicine , pathology
Alan Sargeson was an extraordinarily gifted inorganic chemist who consistently made important and lasting contributions to his discipline. His lifelong interests were in the area of coordination chemistry, especially in the stereochemistry and reactivity of complexes involving the transition element cobalt. Notable discoveries included the elucidation of the mechanisms of substitution reactions of cobalt complexes, the demonstration that amino acid amides and their esters and phosphate esters incorporated in properly designed metal complexes could achieve the high rates of hydrolysis displayed by enzyme reactions, and perhaps most notably the discovery of the ready formation of cage complexes in which the metal is fully encapsulated. His impact on his field was far reaching, his achievements were at the highest level and for more than 30 years he was among the few who dominated the field.

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