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Each of the enantiomers of [Ru(phen)2(dppz)]2+ (phen = 1,10-phenanthroline, dppz = dipyrido[3,2-a:2',3'-c]phenazine) complex was attached to the 5' end of the short oligonucleotide to form a pair of the conjugates. The delta-isomer of them showed a high cooperativity in tandem hybridization to the repetitive sequence, while the lambda-isomer did not.

Asymmetric cooperativity in tandem hybridization of the DNA conjugates bearing chiral metal complexes