Enantiomer Separation of a Novel Aminothiazolecarboxamide Fungicide Using Polysaccharide-Derived Chiral Stationary Phases | Zendy

B.-H. Kim | Zendy; Sang Uck Lee | Zendy

Open Access

Enantiomer Separation of a Novel Aminothiazolecarboxamide Fungicide Using Polysaccharide-Derived Chiral Stationary Phases

Author(s) -

B.-H. Kim,

Sang Uck Lee

Publication year - 2005

Publication title -

journal of chromatographic science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.362

H-Index - 56

eISSN - 1945-239X

pISSN - 0021-9665

DOI - 10.1093/chromsci/43.10.501

Subject(s) - chemistry , enantiomer , polysaccharide , elution , chromatography , resolution (logic) , chiral stationary phase , fungicide , chirality (physics) , chiral column chromatography , column chromatography , organic chemistry , botany , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark , artificial intelligence , computer science , biology

The direct enantioseparation of a novel aminothiazolecarboxamide fungicide, ethaboxam, on polysaccharide-derived chiral stationary phases (CSPs) is described. Good resolution is achieved with several polysaccharide-derived CSPs. Chiralcel OD (OD-H) and Chiralpak AS are excellent for direct enantiomer separation of ethaboxam. The elution behavior and the effects of eluent composition on the resolution of ethaboxam are also investigated. Furthermore, the mechanism for chiral recognition using molecular mechanics is discussed.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research