Pilot-Scale Validation of a New Sensor for On-Line Analysis of Volatile Fatty Acids and Alkalinity in Anaerobic Wastewater Treatment Plants
Author(s) -
Francisco Molina,
Gonzalo Ruíz-Filippi,
C. de la Cruz Garcia,
Juan M. Lema,
Enrique Roca
Publication year - 2009
Publication title -
environmental engineering science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.46
H-Index - 65
eISSN - 1557-9018
pISSN - 1092-8758
DOI - 10.1089/ees.2007.0308
Subject(s) - alkalinity , bicarbonate , wastewater , chemistry , anaerobic digestion , sewage treatment , pulp and paper industry , anaerobic exercise , spectrum analyzer , waste management , environmental science , environmental engineering , methane , engineering , physiology , organic chemistry , biology , electrical engineering
This paper describes a validation procedure applied for an on-line titrimetric analyzer (AnaSense ® -Anaerobic Control Analyzer) prototype designed to detect of volatile fatty acids (VFA) and alkalinity (bicarbonate). The AnaSense ® analyzer was recently developed under the framework of the TELEMAC European Project. A pi- lot-scale evaluation of the analyzer was carried out in an anaerobic wastewater treatment plant, in a hybrid Upflow Sludge Bed Filter (USBF) reactor with an overall volume of 1.15 m 3 . The sensor uses two methods, both based on two-point titrimetric analyses, for determining VFA and alkalinity concentration. AnaSense ® per- formed on-line monitoring of VFA (13-4,900 mgL 1 ) and bicarbonate (2.5-49.5 mEqL 1 ), and demonstrated sufficient accuracy for both VFA and bicarbonate detection. Intermediate Alkalinity/Total Alkalinity (IA/TA) and Intermediate Alkalinity/Partial Alkalinity (IA/PA) ratios were also evaluated to test the suitability of the sensor for anaerobic digestion process control.
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