The influence of the temperature on the mechanical properties of Sanicro 25 steel

Austenitic steel 22Cr25NiWCoCu (Sanicro 25) is one of the newest and most promising steels for use in supercritical and ultra-supercritical power units. High resistance of Sanicro 25 steel to corrosion and oxidation in the steam atmosphere at up to 700 °C is ensured by chromium content at 21.5-23.5 wt%. Also, higher chromium content provides less mass decrement during high-temperature corrosion at 700 °C. Currently, the Sanicro 25 steel is characterised by the highest creep strength among the commercially used creep-resistant stainless steels. In this work, the study of precipitation processes and microstructure stability in the delivery state and after the ageing process in time up to 20,000 h at 750 °C was performed. Identification of secondary phases was performed using electron diffraction on thin films using transmission electron microscopy and X-ray phase composition analysis. Long-term ageing depending on time and temperature showed that there are four secondary phases in Sanicro 25: M 23 C 6 , MX, NbCrN, σ-phase and Cu_rich. The precipitation and increase in the size of secondary phase particles during ageing results in a decrease in matrix saturation with alloying elements, which leads to a reduction in hardening by solid solution mechanism. These processes and effects result in changes in mechanical properties. The alloy overageing effect observed for the ageing temperature of 750 °C results in obtaining strength properties similar to those of the steel in the as-received condition.