Open AccessSynthesis of highly stable dual-site immobilized ruthenium olefin metathesis catalyst without ru leaching
Author(s) -
Huanhuan Zhao,
Yanwu Zhang
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/2131/4/042055
Subject(s) - ruthenium , catalysis , ring opening metathesis polymerisation , dichloromethane , metathesis , leaching (pedology) , chemistry , combinatorial chemistry , salt metathesis reaction , polymerization , olefin fiber , polymer chemistry , ring closing metathesis , organic chemistry , solvent , polymer , environmental science , soil science , soil water
The tri-block copolymer is used as a carrier to simultaneously immobilize the N-heterocyclic and benzylidene ligands precursor of the Ru-based catalyst to form a dual-site immobilized catalyst. The dual-site immobilized catalyst can catalyze ring-opening metathesis polymerization, ring-closing metathesis and self-metathesis. The dual-site immobilized catalyst shows good heterogeneity in dichloromethane, which simplifies the purification of product and recovery of catalyst. The dual-site immobilized catalyst exhibits excellent activity and recycling performance. The excellent recyclability can be attributed to the capture of ruthenium by the excess ligands precursor on carrier. Importantly, ruthenium residues are not detected in product.