The Organic Refractory Material in the Diffuse Interstellar Medium: Mid‐Infrared Spectroscopic Constraints

This is an analysis of the 4000¨1000 cm~1 (2.5¨10 km) region of the spectrum of diÜuse interstellar medium (DISM) dust compared with the spectra of 13 materials produced in the laboratory which serve as analogs to the interstellar material. The organic signatures of extragalactic dust, carbonaceous chon- dritic material, and E. coli bacteria are also presented because these have been discussed in the literature as relevant to the diÜuse interstellar medium. Spectral analysis of the DISM allows us to place signi—- cant constraints on the applicability of proposed candidate materials. The spectra of candidate materials are evaluated using four spectral characteristics based on the interstellar data: (i) comparisons of the pro—le and subpeak positions of the 2940 cm~1 (3.4 km) aliphatic CH stretching-mode band, (ii) the ratio of the optical depth (O.D.) of the aliphatic CH stretch to the O.D. of the OH stretch near 3200 cm~1 (3.1 km), (iii) the ratio of the O.D. of the aliphatic CH stretch to the O.D. of the carbonyl band near 1700 cm~1 (5.9 km), and (iv) the ratio of the O.D. of the aliphatic CH stretch feature to the O.D. of the CH deformation modes near 1470 cm~1 (6.8 km) and 1370 cm~1 (7.25 km). We conclude that the organic refractory material in the diÜuse interstellar medium is predominantly hydrocarbon in nature, possessing little nitrogen or oxygen, with the carbon distributed between the aromatic and aliphatic forms. Long alkane chains with n much greater than 4 or 5 are not major constituents H 3 Cw(CH 2 ) n w of this material. Comparisons to laboratory analogs indicate the DISM organic material resembles plasma processed pure hydrocarbon residues much more so than energetically processed ice residues. This result is consistent with a birth site for the carrier of the 3.4 km band in the out—ow region of evolved carbon stars. The organic material extracted from the Murchison carbonaceous meteorite and the spectrum of E. coli bacteria reveal spectral features in the 5¨10 km region that are absent in the DISM. Although the presence of unaltered circumstellar components in the Murchison meteorite has been established through several lines of evidence, it is unclear whether or not the aliphatic component which gives rise to the 3.4 km band is in that category. Considering the complete 2¨10 km wavelength region, there is no spectral evidence for a biological origin of the 3.4 km interstellar absorption band. The similarity of the aliphatic CH stretch region of dust from our own Galaxy compared with that of distant galaxies suggests that the organic component of the ISM is widespread and may be an important universal reservoir of prebiotic organic carbon. Subject headings: infrared: ISM: lines and bandsISM: moleculesmolecular data