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Studies on Fluorescence Efficiency and Photodegradation of Rhodamine 6G Doped PMMA Using a Dual Beam Thermal Lens Technique
Author(s) -
Achamma Kurian,
Nibu A. George,
B. D. Paul,
V. P. N. Nampoori,
C. P. G. Vallabhan
Publication year - 2002
Publication title -
laser chemistry
Language(s) - English
Resource type - Journals
eISSN - 1026-8014
pISSN - 0278-6273
DOI - 10.1080/02786270215153
Subject(s) - rhodamine 6g , photodegradation , fluorescence , quantum yield , photochemistry , chemistry , methyl methacrylate , rhodamine , rhodamine b , quenching (fluorescence) , analytical chemistry (journal) , dye laser , doping , laser , optics , materials science , polymer , optoelectronics , chromatography , organic chemistry , polymerization , photocatalysis , physics , catalysis
In this paper we report the use of the dual beam thermal lens technique as a quantitative method to determine absolute fluorescence quantum efficiency and concentration quenching of fluorescence emission from rhodamine 6G doped Poly(methyl methacrylate) (PMMA), prepared with different concentrations of the dye. A comparison of the present data with that reported in the literature indicates that the observed variation of fluorescence quantum yield with respect to the dye concentration follows a similar profile as in the earlier reported observations on rhodamine 6G in solution. The photodegradation of the dye molecules under cw laser excitation is also studied using the present method.

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