Intramolecular energy transfer and molecular conformation. | Zendy

Robert E. Dale | Zendy; J. Eisinger | Zendy

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Intramolecular energy transfer and molecular conformation.

Author(s) -

Robert E. Dale,

J. Eisinger

Publication year - 1976

Publication title -

proceedings of the national academy of sciences

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.011

H-Index - 771

eISSN - 1091-6490

pISSN - 0027-8424

DOI - 10.1073/pnas.73.2.271

Subject(s) - intramolecular force , energy transfer , range (aeronautics) , macromolecule , chemical physics , förster resonance energy transfer , acceptor , degrees of freedom (physics and chemistry) , chemistry , physics , materials science , optics , thermodynamics , stereochemistry , fluorescence , condensed matter physics , biochemistry , composite material

A discussion of the range of applicability of Forster long-range energy transfer in the determination of macromolecular dimensions and conformational dynamics is given. Emphasis is laid on the effect of restrictions in the orientational freedom of donor and acceptor and on the importance of the orientational averaging regime. The usefulness and limitations of polarized emission measurements in this regard are discussed.

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