One- and Two-Fluid van der Waals Theories of Liquid Mixtures, II. 6:12 Molecules | Zendy

Douglas Henderson | Zendy; Peter Leonard | Zendy

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One- and Two-Fluid van der Waals Theories of Liquid Mixtures, II. 6:12 Molecules

Author(s) -

Douglas Henderson,

Peter Leonard

Publication year - 1971

Publication title -

proceedings of the national academy of sciences

Language(s) - English

Resource type - Journals

eISSN - 1091-6490

pISSN - 0027-8424

DOI - 10.1073/pnas.68.3.632

Subject(s) - van der waals force , van der waals equation , van der waals radius , theorem of corresponding states , van der waals surface , van der waals strain , thermodynamics , equation of state , molecule , hamaker constant , chemistry , physics , quantum mechanics

The equation of state of mixture of 6:12 molecules is calculated using the one- and two-fluid van der Waals theories, the three-fluid theory, and the Flory theory. The one-fluid van der Waals theory is found to be in the best agreement with the quasi-experimental, machine-simulation results.

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